How much ozone is above us
Scientists are seeing signs that the ozone hole now seems to have reached its maximum extent. After the unusually small and short-lived ozone hole in , which was driven by special meteorological conditions, we are registering a rather large one again this year, which confirms that we need to continue enforcing the Montreal Protocol banning emissions of ozone depleting chemicals.
The Montreal Protocol bans emissions of ozone depleting chemicals. Since the ban on halocarbons, the ozone layer has slowly been recovering; the data clearly show a trend in decreasing area of the ozone hole. The large ozone hole in has beendriven by a strong, stable and cold polar vortex, which kept the temperature of the ozone layer over Antarctica consistently cold. Ozone depletion is directly related to the temperature in the stratosphere, which is the layer of the atmosphere between around 10 km and round 50 km altitude.
These polar stratospheric clouds contain ice crystals that can turn non-reactive compounds into reactive ones, which can then rapidly destroy ozone as soon as light from the sun becomes available to start the chemical reactions.
Stratospheric ozone concentrations have been observed to have reduced to near-zero values over Antarctica around 20 to 25 km of altitude hPa , with the ozone layer depth coming just below Dobson Units, about a third of its typical value outside of ozone hole events. Paulson School of Engineering and Applied Sciences SEAS and the Department of Earth and Planetary Sciences , found that stratospheric ozone concentrations over the United States in summer are vulnerable to both increases in water vapor and observed variations in temperature from storm systems over the Great Plains.
Increased frequency and intensity of these storm systems, as well as longer-term decreases in stratospheric temperatures, are expected to accompany climate change. Then they employed recent NEXRAD weather radar observations to demonstrate that on average storms each summer penetrate into the stratosphere over the central United States, which is far more frequent than was previously thought. This combination of circumstances puts the stratosphere over states including Texas, Oklahoma, Kansas, Nebraska, Iowa, Missouri, the Dakotas and states that border the Great Plains, at risk for chemical reactions that deplete ozone during summer, potentially leading to higher levels of exposure to damaging UV light from the sun.
Molina of the University of California San Diego, the Nobel Prize winner in stratospheric chemistry, who was not involved in this research.
Stratospheric ozone is one of the most delicate aspects of habitability on the planet. There is only marginally enough ozone in the stratosphere to provide protection from UV radiation for humans, animals and crops. Medical research specific to the United States has determined that a 1 percent decrease in the amount of ozone in the stratosphere corresponds to a 3 percent increase in the incidence of human skin cancer.
There are now 3. Thus, for each 1 percent reduction in ozone, there would be an additional , new cases of skin cancer annually in the United States. Homeyer of the University of Oklahoma, a co-investigator on the paper. The results strongly motivate the need for increased meteorological and chemical observations of such storms. We don't yet know just how close we are to reaching that threshold.
The scientific community has observed the chemical reactions that attack ozone over the polar regions in winter, but the important combination of observations that define the cause and the rate of stratospheric ozone loss have never been made over the central US in summer. These processes are well understood and predictable. Each natural reduction in ozone levels has been followed by a recovery.
Beginning in the s, however, scientific evidence showed that the ozone shield was being depleted well beyond natural processes. When chlorine and bromine atoms come into contact with ozone in the stratosphere, they destroy ozone molecules.
One chlorine atom can destroy over , ozone molecules before it is removed from the stratosphere. Ozone can be destroyed more quickly than it is naturally created. Some compounds release chlorine or bromine when they are exposed to intense UV light in the stratosphere. These compounds contribute to ozone depletion, and are called ozone-depleting substances ODS ODS A compound that contributes to stratospheric ozone depletion.
ODS include chlorofluorocarbons CFCs , hydrochlorofluorocarbons HCFCs , halons, methyl bromide, carbon tetrachloride, hydrobromofluorocarbons, chlorobromomethane, and methyl chloroform. ODS are generally very stable in the troposphere and only degrade under intense ultraviolet light in the stratosphere. When they break down, they release chlorine or bromine atoms, which then deplete ozone.
ODS that release chlorine include chlorofluorocarbons chlorofluorocarbons Gases covered under the Montreal Protocol and used for refrigeration, air conditioning, packaging, insulation, solvents, or aerosol propellants. Since they are not destroyed in the lower atmosphere, CFCs drift into the upper atmosphere where, given suitable conditions, they break down ozone. These gases are being replaced by other compounds: hydrochlorofluorocarbons, an interim replacement for CFCs that are also covered under the Montreal Protocol, and hydrofluorocarbons, which are covered under the Kyoto Protocol.
All these substances are also greenhouse gases. See hydrochlorofluorocarbons, hydrofluorocarbons, perfluorocarbons, ozone depleting substance. CFCs , hydrochlorofluorocarbons hydrochlorofluorocarbons Compounds containing hydrogen, fluorine, chlorine, and carbon atoms. Although ozone depleting substances, they are less potent at destroying stratospheric ozone than chlorofluorocarbons CFCs. They have been introduced as temporary replacements for CFCs and are also greenhouse gases.
See ozone depleting substance. HCFCs , carbon tetrachloride carbon tetrachloride A compound consisting of one carbon atom and four chlorine atoms. Carbon tetrachloride was widely used as a raw material in many industrial uses, including the production of chlorofluorocarbons CFCs , and as a solvent. Solvent use ended when it was discovered to be carcinogenic. It is also used as a catalyst to deliver chlorine ions to certain processes.
Its ozone depletion potential is 1. Methyl chloroform is used as an industrial solvent. Its ozone depletion potential is 0. ODS that release bromine include halons halons Compounds, also known as bromofluorocarbons, that contain bromine, fluorine, and carbon. They are generally used as fire extinguishing agents and cause ozone depletion. Bromine is many times more effective at destroying stratospheric ozone than chlorine. Methyl Bromide is an effective pesticide used to fumigate soil and many agricultural products.
Because it contains bromine, it depletes stratospheric ozone and has an ozone depletion potential of 0. Production of methyl bromide was phased out on December 31, , except for allowable exemptions. In the s, concerns about the effects of ozone-depleting substances ODS ODS A compound that contributes to stratospheric ozone depletion.
Gaseous CFCs can deplete the ozone layer when they slowly rise into the stratosphere, are broken down by strong ultraviolet radiation, release chlorine atoms, and then react with ozone molecules. See Ozone Depleting Substance. Aerosols are emitted naturally e.
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